University of Nevada Las Vegas

 

MEG301 Structures and Properties of Solids

 

Department of Mechanical Engineering

 

Fall Semester 2000

 

ATOMIC AND MOLECULAR BONDS

 

 

Primary Atomic Bonds

Ionic bonds

Covalent bonds

Metallic bonds

 

Ionic bonds: relatively large interatomic forces are set up by an electron transfer from one atom to another to produce ions which are bonded together by coulombic forces. Characteristics: strong, nondirectional.

Covalent bonds: relatively large interatomic forces are created by the sharing of electrons to form a bond with a localized direction. Characteristics: strong, directional.

Metallic bonds: relatively large interatomic forces are created by the sharing of electrons in a delocalized manner to form strong nondirectional bonding between atoms. Characteristics: strong, nondirectional.

 

Secondary Atomic and Molecular Bonds

Permanent dipole bonds

Fluctuating dipole bonds

 

Permanent dipole bonds: relatively weak intermolecular bonds are formed between molecules which posses permanent dipoles. A dipole in a molecule exists due to asymmetry in its electron density distribution. Characteristics: weak, dipoles.

Fluctuating dipole bonds: very weak electronic dipole bonding can take place among atoms due to the asymmetrical distribution of electron densities around their nuclei. Characteristics: very weak, fluctuating.

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Created by Dr. Wang